Enantiomer-Selective Radical Polymerization
نویسندگان
چکیده
منابع مشابه
Binaphthol-derived phosphoric acids as efficient chiral organocatalysts for the enantiomer-selective polymerization of rac-lactide.
A high enantiomer-selectivity for the polymerization of rac-lactide was achieved using chiral binaphthol-derived monophosphoric acids as organocatalysts. During the polymerization, d-lactide (DLA) preferentially polymerized via kinetic resolution with the maximum selectivity factor (kD/kL) of 28.3. The selective polymerization of DLA was derived from a dual activation, i.e., monomer activation ...
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ژورنال
عنوان ژورنال: Kobunshi
سال: 2006
ISSN: 0454-1138,2185-9825
DOI: 10.1295/kobunshi.55.275